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In the title complex, {[Cu(C 11 H 16 N 4 ) 2 (H 2 O) 2 ](C 10 H 6 O 6 S 2 )}  n  , the Cu II  atom, lying on an inversion center, is six-coordinated by two water mol­ecules and four N atoms from four 1,5-bis­(1 H -imidazol-1-yl)pentane (biim-5) ligands in a distorted octa­hedral geometry. Adjacent Cu II  atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Inter­molecular O—H⋯O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11).

acta crystallographica. section e

catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]