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The asymmetric unit of the title hydrated salt, C 18 H 40 N 4 P + ·Cl − ·2H 2 O, consists of two ionic mol­ecules and four water mol­ecules. The mol­ecular geometry around the penta­coordinate P atom is trigonal–bipyramidal, with a H atom and an apical N atom in axial positions and three N atoms with isobutyl substituents in equatorial positions. The Cl −  ions and water mol­ecules are connected  via  O—H⋯Cl hydrogen bonds, forming chains along [100]. The ethyl­ene bridging groups are disordered with refined site-occupancy ratios of 0.578 (9):0.422 (9).

2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1λ5-phosphatricyclo[3.3.3.01,5]undecan-5-ium chloride dihydrate

2,8,9-Tris(2-methylpropyl)-2,5,8,9-tetraaza-1λ⁵-phosphatricyclo[3.3.3.0^1,5]undecan-5-ium chloride dihydrate