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Dipraseodymium molybdenum scandium hepta­oxide, Pr 2 Mo 1.73 Sc 0.27 O 7 , crystallizes in the cubic pyrochlore-type structure. In the crystal, (Mo,Sc)O 6  octa­hedra are linked together by common corners, forming a three-dimensional [(Mo,Sc) 2 O 6 ] framework. The Pr atom and another O atom atom are located in the voids of this framework. The Mo and the Sc atom are distributed statistically over the same 16 d  crystallographic position, with site-occupancy factors of 0.867 (3) and 0.133 (3), respectively. The Pr 3+  ions are surrounded by six O atoms from the MoO 6  octa­hedra and by two other O atoms, forming a ditrigonal scalenohedron. All atoms lie on special positions. The Pr and the statistically distributed (Mo,Sc) sites are in the 16 c  and 16 d  positions with .-3 m  symmetry, and two O atoms are in 48 f  and 8 a  positions with 2. mm  and -43 m  site symmetry, respectively.

The pyrochlore-type molybdate Pr2Mo1.73Sc0.27O7

The pyrochlore-type molybdate Pr₂Mo_1.73Sc_0.27O₇