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In the title solvated salt, [Ag(C 18 H 15 P) 4 ](CF 3 CO 2 )·C 2 H 5 OH, the Ag I  atom is coordinated by four P atoms from triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenyl­phosphane ligands, two each have an equally disordered phenyl ring while the Ag I  atom is disordered over two positions in a 0.9595 (15):0.0405 (15) ratio and the trifluoro­acetate anion is equally disordered over two positions with respect to the lattice ethanol mol­ecule.

Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate