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In the title complex, [Co(C 10 H 7 O 4 ) 2 (C 12 H 12 N 2 )(H 2 O) 2 ]  n  , the Co II  ion is located on a crystallographic centre of symmetry and is six-coordinated by two N atoms from two 1,2-bis­(4-pyrid­yl)ethane ligands, two carboxylate O atoms from two 1,3-dihydro-3-oxo-1-isobenzofuran­acetate ligands and two terminal water ligands. The 1,2-bis(4-pyrid­yl)ethane ligands act as bidentate ligands, and bridge the Co II  ions into infinite chains extending parallel to [010]. In these chains, there are intra-mol­ecular O—H⋯O hydrogen bonding between the coordination water mol­ecules and carboxyl­ate groups. Inter-mol­ecular O—H⋯O hydrogen bonding between the adjacent chains and π⋯π stacking inter­actions result in the formation of a three-dimensional supra­molecular network.

acta crystallographica. section e

catena-Poly[[diaquabis[2-(3-oxo-1,3-dihydro-2-benzofuran-1-yl)acetato-κO]cobalt(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ2N:N′]