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In the crystal of the title compound, [Ru(C 2 H 6 NS)(C 26 H 24 P 2 ) 2 ]PF 6 , the Ru II  atom is in a slightly distorted octa­hedral geometry, coordinated by one 2-amino­ethane­thiol­ate (aet) and two 1,2-bis­(diphenyl­phosphan­yl)ethane (dppe) ligands. The crystal consists of a pair of enanti­omers (Δ and Λ) of the compound. The Δ and Λ isomers have the λ and δ conformations for the aet chelate rings and the δ and λ conformations for the dppe chelate rings. The F atoms of the PF 6   −  counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.

acta crystallographica. section e

(2-Aminoethanethiolato-κ2N,S)bis[1,2-bis(diphenylphosphanyl)ethane-κ2P,P′]ruthenium(II) hexafluoridophosphate