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The title dimeric zirconium complex, [Zr 2 (C 20 H 24 ) 2 S 2 ]·C 7 H 8 , was obtained from the reaction of (ebthi)Zr(η 2 -Me 3 Si–C 2 –SiMe 3 ) [ebthi is  rac -1,2-bis­(η 5 -4,5,6,7-tetra­hydro­inden-1-yl)ethane] and S=C=N-ada (ada = adamantan-1-yl) along with the formation of the isonitrile C N-ada. Each Zr IV  atom is coordinated by the sterically hindered ebthi ligand and two μ-sulfide ligands in a strongly distorted tetra­hedral geometry. The [ZrS] 2  unit is almost planar (mean deviation from the best plane of the four atoms = 0.025 Å). A –CH 2 —CH 2 – group in one ebthi ligand was disordered over two sites, with refined occupancy factors of 0.551 (6) and 0.449 (6). The asymmetric unit also contains a toluene solvent mol­ecule.

Di-μ-sulfido-bis{[rac-1,2-bis(η5-4,5,6,7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvate

Di-μ-sulfido-bis{[rac-1,2-bis(η⁵-4,5,6,7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvate