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In the title compound, [CoBr 2 (C 14 H 12 N 2 )]·CH 3 CN, the Co II  atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.828 (5), 3.782 (5), 3.880 (5) and 3.646 (5) Å] stabilize the structure.

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)cobalt(II) acetonitrile monosolvate

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)cobalt(II) acetonitrile monosolvate