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In the crystal structure of the title compound, {[Cu(C 6 H 2 O 5 )(C 10 H 8 N 2 )(H 2 O)]·2H 2 O}  n  , an infinite chain parallel to [110] is formed by the linking of Cu(H 2 O)(2,2′-bipyridine) units through a furan-2,5-dicarboxyl­ate bridge. The Cu II  atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl­ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol­ecule is 83.88 (7)°. O water —H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).

acta crystallographica. section e

catena-Poly[[[aqua(2,2′-bipyridine-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5] dihydrate]