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The Sn IV  atom in the centrosymmetric title complex, [Sn 2 (CH 3 ) 4 (NCS) 2 (OH) 2 ], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio­cyanate anion are in the apical >positions. The dinuclear species are linked through O—H⋯S and C—H⋯ S hydrogen-bonding inter­actions into a three-dimensional network.

Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]