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The asymmetric unit of the title compound, C 18 H 26 O 5 , which is known as α-zearalanol, contains two mol­ecules having the same conformation, with a r.m.s. deviation of less than 0.03 Å for all non-H atoms. In each independent mol­ecule, an intra­molecular O—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules, forming infinite chains along [110] and [1-10].

(3S,7R)-7,14,16-Trihydroxy-3-methyl-3,4,5,6,7,8,9,10,11,12-decahydro-1H-2-benzoxacyclotetradecin-1-one.