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In the title compound, [Sn 2 (C 4 H 9 ) 4 (C 6 H 6 PO 3 ) 4 ]  n  , the basic unit is a dimer containing two symmetry-related Sn IV  atoms bridged by two hydrogenphenylphosphonate anions. This fragment is located about an inversion center, and each Sn IV  atom is linked to two other hydrogenphenylphosphonate anions, giving a layered structure parallel to (010). The coordination geometry for the Sn IV  atoms is close to octa­hedral. The layers are connected  via  O—H⋯O hydrogen bonds, generating a three-dimensional network. One butyl group is disordered over two sets of sites, with occupancies of 0.49 (2) and 0.51 (2).

Poly[tetrabutyltetrakis(μ2-hydrogen phenylphosphonato)ditin(IV)]

Poly[tetrabutyltetrakis(μ₂-hydrogen phenylphosphonato)ditin(IV)]