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In the title compound, [Pd 2 Cl 4 (C 8 H 6 N 4 )]·C 3 H 7 NO, the two Pd 2+  cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2′-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd 2+  cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter­section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol­ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol­ecule are disordered over two sets of sites of equal occupancy.

μ-(2,2′-Bipyrimidine)-bis[dichloridopalladium(II)] dimethylformamide monosolvate