English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

In the title compound, [Ru(3)(C(25)H(23)N)(C(5)H(5))(3)]·3PF(6)·2C(3)H(6)O], the cation is a triruthenium complex of a 9,10-dihydro-anthracene derivative. Three RuCp(+) (Cp is cyclo-penta-dien-yl) groups are bonded to the three aromatic rings of the ligand. Surprisingly, the pyramidalized N atom of the heterocycle (Σ C-N-C = 329.0°) points towards the anthracenyl group, so losing its coordinative ability. There is an inter-molecular C-H⋯π inter-action involving an acetone mol-ecule and the adjacent benzyl ring of the ligand. In the crystal, mol-ecules are linked via a number of C-H⋯O and C-H⋯F inter-actions and a C-H⋯π inter-action, leading to the formation of a three-dimensional supra-molecular structure. One of the Cp groups is disordered over two positions, with refined occupancies of 0.695 (14):0.305 (14). Two of the three hexa-fluoro-phospate anions are disordered, with refined occupancies of 0.630 (6):0.370 (6) and 0.771 (8):0.229 (8). One of the two solvent acetone mol-ecules is also disordered, with refined occupancies of 0.82 (2):0.18 (2).

acta crystallographica. section e

Tris(η5-cyclopentadienyl)-tris[η6-[9,10-dihydroanthracene-9,10-endo-3′,4′-(N-benzyl)pyrrolidine]]triruthenium(II) tris(hexafluorophosphate) acetone disolvate