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In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra-oxo-4,10-diaza-tetra-cyclo-[5.5.2.0(2,6).0(8,12)]tetra-dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The other Ag(I) ion, lying on an inversion center, is coordinated by two O atoms from two L ligands and two N atoms from two 1,4-bis-(imidazol-1-ylmeth-yl)benzene ligands in a distorted square-planar geometry. An additional Ag⋯Ag [3.0119 (3) Å] inter-action links the Ag(I) ions into a chain along [010]. The two types of ligands have mirror symmetry and connect the Ag(I) ions into a layer parallel to (100).

acta crystallographica. section e

Poly[[μ2-1,4-bis(imidazol-1-ylmethyl)benzene](μ4-3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.02,6.08,12]tetradec-13-ene-4,10-diido)disilver(I)]