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In the title complex, {[Zn(NCS) 2 (C 15 H 15 N 9 ) 2 ]·H 2 O}  n  , the Zn II  ion is located on an inversion centre and is six-coordinated in a distorted octa­hedral geometry, coordinated by N atoms from four bridging 1,3,5-tris­(1,2,4-triazol-1-ylmeth­yl)benzene (ttmb) ligands and two terminal SCN −  counter-anions. Two of the three triazol groups in each ttmb ligand link the Zn II  atoms, forming a looped-chain structure along [0-11]. The lattice water molecule shows half-occupancy due to disorder around an inversion centre.

acta crystallographica. section e

catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ2N4:N4′]] monohydrate]