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In the title compound, [CuI(C 8 H 8 N 2 S)(C 18 H 15 P) 2 ]·CH 3 OH, the coordination environment around the Cu I  atom is distorted tetra­hedral, defined by two P atoms of two triphenyl­phosphane ligands, one S atom of a 5-methyl-1 H -benzimidazole-2(3 H )-thione ligand and one I atom. The complex mol­ecules and the methanol solvent mol­ecules are connected  via  N—H⋯O and O—H⋯I hydrogen bonds, forming a chain along [010]. An intra­molecular N—H⋯I hydrogen bond is also observed.

Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate