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The crystal structure of the polymeric title complex, [Zn(C 14 H 8 O 4 )]  n  , is composed of layers parallel to (110) formed by linking of Zn–carboxyl­ate chains with biphenyl units of the biphenyl-2,4′-dicarboxyl­ate (bpdc) ligands. The Zn II  atom is five-coordinated in a distorted square-pyramidal geometry by five O atoms from four bpdc ligands. The dihedral angle between the benzene rings is 52.32 (12)°.

Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]

Poly[(μ₄-biphenyl-2,4′-dicarboxylato-κ⁵O²:O^2′:O⁴:O⁴,O^4′)zinc]