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In the title complex, [Ag 2 (C 12 H 8 N 2 O 4 )(C 10 H 8 N 2 ) 2 ]·2H 2 O, the Ag I  ion is three-coordinated by two N atoms from a chelating 2,2′-bipyridine ligand and one N atom from an imide ligand in a Y-shaped fashion. The imide ligand and the complex lie on a twofold rotation axis. The ligand bridges two Ag I  ions, forming a dinuclear complex. In the crystal, O—H⋯O hydrogen bonds link the lattice water mol­ecules and the complex mol­ecules into a ribbon-like structure along [001]. π–π inter­actions are observed between the pyridine rings [centroid–centroid distance = 3.8289 (14) Å].

acta crystallographica. section e

(μ-3,5,9,11-Tetraoxo-4,10-diazatetracyclo[5.5.2.02,6.08,12]tetradec-13-ene-4,10-diido-κ2N:N′)bis[(2,2′-bipyridine-κ2N,N′)silver(I)] dihydrate