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In the title compound, (C 20 H 26 P) 2 [Pd 2 Cl 6 ], the Pd II  atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phospho­nium cation. Only weak C—H⋯π inter­actions are present in the crystal structure.

Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butylphosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]