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In the title complex, [Pt(C(15)H(11)N(4)O)Cl(3)]·CH(3)CN, the Pt(IV) ion adopts a distorted octa-hedral coordination geometry defined by a tridentate cyclo-metalated NCN ligand and three Cl atoms. In the crystal, individual mol-ecules are aggregated into a three-dimensional network by C-H⋯Cl hydrogen-bonding inter-actions and π-π stacking inter-actions between the tridentate ligands, the shortest ring centroid-centroid distance being 3.613 Å.

Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC1]platinum(IV) acetonitrile monosolvate

Trichlorido[4-methoxy-2,6-bis(2-pyrimidin-2-yl-κN)phenyl-κC¹]platinum(IV) acetonitrile monosolvate