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The structure of the title complex, [ReBr(C 13 H 19 OP)(CO) 3 ], displays a facial coordination of the three CO ligands and a κ 2   O , P  coordination mode of the 2-diisopropyl­phosphino­benzaldehyde ligands. The Re—C bond distance for the CO ligand  trans  to the P atom is, due to its  trans  influence, elongated to 1.943 (3) Å, showing that this CO ligand is more weakly bound to the Re centre than the other two.

fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ2O,P]rhenium(I)

fac-Bromidotricarbonyl[2-(diisopropylphosphanyl)benzaldehyde-κ²O,P]rhenium(I)