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In the crystal structure of 1-methyl-3-allyl benzotriazolium iodide, C 10 H 12 N 3   + ·I − , centrosymmetric dimers of coplanar cations are π-stacked with an inter­planar distance of 3.453 (6) Å. The iodide anions are situated above and below the formally positive charged triazolium rings.

3-Allyl-1-methyl-1H-benzotriazol-3-ium iodide