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In the title salt, [Co(C 10 H 6 O 2 )(C 18 H 18 N 4 )](C 24 H 20 B)·C 3 H 6 O·0.5H 2 O, the Co III  ion in the complex cation is six-coordinated in a rigid octahedral N 4 O 2  geometry. The asymmetric unit contains one complete [Co(C 10 H 6 O 2 )(C 18 H 18 N 4 )] +  unit, one tetraphenylborate counter-anion and one acetone and one water molecule that is located on an inversion centre. All the features of the Co III  ion are fully consistent with the formulation of the cation as a Co 3+ –catecholate complex. Variable-temperature magnetic measurements in the region 2–380 K show a obvious diamagnetism over the observed temperature range.

acta crystallographica section e structure reports online

(Naphthalene-2,3-diolato-κ2O,O′)[tris(pyridin-2-ylmethyl)amine-κ4N]cobalt(III) tetraphenylborate acetone monosolvate hemihydrate