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In the title compound, [ZnCl 2 (C 6 H 6 FN) 2 ], the Zn II  atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl −  anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol­ecules are linked  via  pairs of N—H⋯Cl hydrogen bonds, forming chains propagating along the  b  axis. These chains are in turn linked  via  a second pair of N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to the  ab  plane. The title compound crystallizes in the space group  Pca 2 1  and exhibits weak second harmonic generation (SHG) properties.

Dichloridobis(4-fluoroaniline-κN)zinc