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The asymmetric unit of the title compound, [Zn(C 15 H 12 BrN 3 O 2 S)(C 12 H 12 N 2 )]·C 3 H 7 NO, contains two independent mol­ecules with a similar structure. The doubly deprotonated Schiff base ligand  O , N , S -chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2′-bipyridine ligand constitute the square plane of the distorted square pyramid surrounding the metal atom. The apical site is occupied by the second N atom of the substituted 2,2′-bipyridine. The secondary amine group of the Schiff base dianion forms a hydrogen bond to the O atom of the dimethyl­formamide solvent. In the crystal, the phenyl ring of one of the two Schiff base anions is disordered over two positions in a 1:1 ratio. The crystal studied is a racemic twin.

acta crystallographica section e structure reports online

(Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ2O2,N2}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)zincN,N-dimethylformamide monosolvate