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A second monoclinic polymorph of the title mol­ecule, C 15 H 21 FN 3 O 4 P, is reported in the space group  P 2 1 / n  and compared to the previously reported  C 2/ c  space group [Gholivand  et al.  (2006  ▶ ).  Polyhedron ,  25 , 711–721]. The asymmetric unit of the title compound consists of two independent mol­ecules. The P atoms adopt a distorted tetra­hedral environment. In the C(O)NHP(O) fragment, the P=O and the N—H groups are in a  syn  conformation with respect to each other and in the crystal, inter­molecular N—H⋯O=P hydrogen bonds form dimeric aggregates.

A second monoclinic polymorph ofN-[bis(morpholin-4-yl)phosphinoyl]-4-fluorobenzamide with theP21/nspace group

A second monoclinic polymorph ofN-[bis(morpholin-4-yl)phosphinoyl]-4-fluorobenzamide with theP2₁/nspace group