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In the title compound, {[Cd(C 9 H 5 BrO 4 )(C 10 H 8 N 2 )(H 2 O)]·H 2 O}  n  , the Cd II  atom has a distorted octa­hedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxyl­ate O atoms from three 3-bromo-2-(carboxyl­atometh­yl)benzoate (bcb) ligands and one O atom from a water mol­ecule. The bipy and bcb ligands link the Cd II  atoms into a three-dimensional network. O—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and benzene rings [centroid–centroid distance = 3.736 (4) Å] are present in the crystal.

acta crystallographica section e structure reports online

Poly[[aqua(μ2-4,4′-bipyridine-κ2N:N′)[μ3-3-bromo-2-(carboxylatomethyl)benzoato-κ3O1:O1′:O2]cadmium] monohydrate]