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The four six-membered fused rings in the title compound, C 10 H 20 N 6 ·2H 2 O, adopt chair conformations; the H atoms of the four secondary N atoms occupy axial positions. Hydrogen bonds of the types N—H⋯N, N—H⋯O and O—H⋯N link the organic and water mol­ecules into a three-dimensional network.

2,3,9,10,15,16-Hexaazatetracyclo[6.6.2.04,16.011,15]hexadecane dihydrate

2,3,9,10,15,16-Hexaazatetracyclo[6.6.2.0^4,16.0^11,15]hexadecane dihydrate