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In the title mol­ecule, C 13 H 15 N 3 O 9 , the nitro groups are tilted with respect to the benzene mean plane by 22.8 (3) and 31.6 (3)°. The meth­oxy groups are in a  cis  orientation relative to the ring. In the crystal, mol­ecules are linked by strong N—H⋯O hydrogen bonds into  C (3) chains along [100].

(R*)-Methyl 2-(2,6-dimethoxy-3,5-dinitrobenzamido)propanoate