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In the centrosymmetric title compound, [Cu 2 (C 10 H 8 O 4 )Cl 2 (C 10 H 8 N 2 ) 2 (H 2 O) 2 ]·2H 2 O, the Cu II  atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2′-bipyridine ligand, one O atom from a 1,4-phenyl­enediacetate ligand, one Cl atom and one water mol­ecule. The 1,4-phenyl­enediacetate ligand, lying on an inversion center, bridges two Cu II  atoms. In the crystal, O—H⋯O and O—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings [centroid–centroid distance = 3.740 (5) Å] link the complex mol­ecules and uncoordinated water mol­ecules into a three-dimensional network.

acta crystallographica. section e

[μ-2,2′-(1,4-Phenylene)diacetato-κ2O1:O4]bis[aqua(2,2′-bipyridine-κ2N,N′)chloridocopper(II)] dihydrate