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The three-dimensional coordination polymer, [Eu 2 (C 6 H 2 O 4 S) 3 (H 2 O) 4 ]  n  , has been synthesized under hydro­thermal conditions. The asymmetric unit comprises one Eu 3+  cation, two aqua ligands and one and a half thiophene-2,5-dicarboxylate anions (the half-anion being completed by a twofold rotation axis). The Eu 3+  cation is eight-coordinated in a distorted dodeca­hedral geometry. The crystal structure features O—H⋯O hydrogen bonds.

Poly[tetraaquabis(μ4-thiophene-2,5-dicarboxylato)(μ2-thiophene-2,5-dicarboxylato)dieuropium(III)]

Poly[tetraaquabis(μ₄-thiophene-2,5-dicarboxylato)(μ₂-thiophene-2,5-dicarboxylato)dieuropium(III)]