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In the title complex, [V(C 13 H 15 NO 3 )O(CH 3 O)(CH 3 OH)], the V V  atom is six-coordinated by a tridentate  O , N , O ′-donor ligand, derived from the condensation of salicyl­aldehyde and  l -isoleucine, a vanadyl O atom, a methano­late O atom and a methanol O atom in a distorted octa­hedral geometry. The asymmetric unit contains two complex mol­ecules. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds connect the mol­ecules into a one-dimensional chain along [100].

(Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)isoleucinato-κ3O,N,O′]vanadium(V)

(Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)isoleucinato-κ³O,N,O′]vanadium(V)