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In the title binuclear centrosymmetric complex, [Cu 2 I 2 (C 8 H 6 N 4 )(C 18 H 15 P) 2 ]·2C 3 H 7 NO, the bis-bidentate 2,2′-bipyrimidine ligand bridges two copper(I) ions, each additionally bound to an iodide anion and a triphenyl­phosphane ligand in a distorted tetra­hedral N 2 IP geometry. The complex mol­ecules pack in columns parallel to [100] generating cavities occupied by dimethyl­formamide solvent mol­ecules. Weak C—H⋯I hydrogen-bonding inter­actions help to stabilize the crystal packing.

acta crystallographica. section e

μ-2,2′-Bipyrimidine-κ4N1,N1′:N3,N3′-bis[iodido(triphenylphosphane-κP)copper(I)] dimethylformamide disolvate