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In the title compound, {[La(C 6 H 4 NO 2 ) 2 (H 2 O) 4 ]Cl}  n  , the La III  atom lies on a twofold rotation axis and is eight-coordinated by four O atoms from four isonicotinate ligands and four water mol­ecules in a distorted square-anti­prismatic coodination environment. Adjacent La III  atoms are bridged by two carboxyl­ate groups from two isonicotinate ligands, forming an extended chain along [001]. These chains are linked through O—H⋯N hydrogen bonds into a three-dimensional network with channels in which the chloride anions form O—H⋯Cl hydrogen bonds. Intra­chain O—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.908 (2) Å] are also observed.

catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ4O:O′] chloride]

catena-Poly[[[tetraaqualanthanum(III)]-di-μ-isonicotinato-κ⁴O:O′] chloride]