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The title structure, [Ni(C 14 H 8 N 2 O 4 )(H 2 O) 4 ]·4H 2 O, contains a mononuclear Ni II  complex formed by a chelating bidentate Schiff base and by four Ni-bonded water mol­ecules. The Ni II  atom is in a distorted octa­hedral coordination by two N atoms in a  cis  disposition [Ni—N = 2.0753 (16) and 2.1048 (16) Å] and by four water O atoms [Ni—O = 2.0500 (15)–2.0822 (15) Å]. The crystal structure is completed by four further non-coordinating water mol­ecules and all constituents are linked in a three-dimensional manner by an extensive system of 16 O—H⋯O hydrogen bonds.

Tetraaqua{5-[(pyridin-2-ylmethylidene)amino]benzene-1,3-dicarboxylato-κ2N,N′}nickel(II) tetrahydrate

Tetraaqua{5-[(pyridin-2-ylmethylidene)amino]benzene-1,3-dicarboxylato-κ²N,N′}nickel(II) tetrahydrate