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In the title compound, C 20 H 28 N 4   2+ ·2PF 6   − , the dihedral angles between the benzene ring and the imidazole rings are 70.18 (11) and 69.83 (11)°, while the imidazole rings form a dihedral angle of 40.52 (12)°. In the crystal, weak C—H⋯F inter­actions link the mol­ecules into a two-dimensional network parallel to (001). A π–π inter­action with a centroid–centroid distance of 3.601 (1) Å is also observed in the crystal structure.

3,3′-Di-n-propyl-1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium) bis(hexafluorophosphate)