English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Reaction of an excess nickel(II) thio-cyanate with pyridazine leads to single crystals of the title compound, [Ni(3)(NCS)(6)(N(2)C(4)H(4))(4)(CH(3)OH)(2)]·4CH(3)OH. The crystal structure consists of trimeric discrete complexes, in which two Ni(II) cations are coordinated by two terminal and one μ-1,1 bridging thio-cyanato anions, one methanol mol-ecule and two bridging pyridazine ligands, whereas the central Ni(II) atom is coordinated by two μ-1,1 bridging anions as well as four bridging pyridazine ligands. The asymmetric unit consists of two crystallographically independent Ni cations, one of which is located on a center of inversion, as well as three crystallographically independent thio-cyanato anions, two pyridazine ligands and three independent methanol mol-ecules in general positions. Two of the solvent mol-ecules do not coordinate to the metal atoms and are located in cavities of the structure. The discrete complexes are linked by inter-molecular O-H⋯O and O-H⋯S hydrogen bonding into layers parallel to the bc plane.

acta crystallographica. section e

Bis(methanol-1κO)tetra-μ-pyridazine-1:2κ4N:N′;2:3κ4N:N′-di-μ-thiocyanato-1:2κ2N:N;2:3κ2N:N-tetrathiocyanato-1κ2N,3κ2N-trinickel(II) methanol tetrasolvate