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In the title complex, [Mn(C 6 H 2 N 3 O 7 ) 2 (C 30 H 26 N 4 O)], the Mn II  atom is coordinated by the tridentate bis-benzimidazole ligand and two atoms of the picrate anions, in a distorted square-pyramidal geometry (τ = 0.038). One nitro O atom of one picrate ion is disordered over two sites with occupancies of 0.54 (5) and 0.46 (5).

[1,1′-Dibenzyl-2,2′-(2-oxapropane-1,3-diyl)di(1H-benzimidazole)-κ3N3,O,N3′]bis(2,4,6-trinitrophenolato-κO1)manganese(II)