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The asymmetric unit of the title complex, [Ni(C 10 H 8 N 2 )(H 2 O) 4 ]SO 4 , consists of a complex [Ni(bipy)(H 2 O) 4 ] 2+  cation (bipy = 2,2′-bipyridine) and a non-coordinating [SO 4 ] 2−  anion. The Ni II  atom is six-coordinated in a distorted octa­hedral geometry defined by the two N atoms of the bipy ligand and four water O atoms. The crystal structure contains extensive classical O—H⋯O hydrogen bonds, which link the ions into a two-dimensional array in the  ab  plane. Layers are connected into a three-dimensional supra­molecular structure by C—H⋯O inter­actions.

Tetraaqua(2,2′-bipyridine-κ2N,N′)nickel(II) sulfate

Tetraaqua(2,2′-bipyridine-κ²N,N′)nickel(II) sulfate