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In the title compound, [MoPb(C 5 H 5 )(CH 3 COO)(CO) 3 ], the Pb II  atom is coordinated pyramidally  via  the Mo 0  atom of a {Cp(CO) 3 Mo} (Cp = cyclo­penta­dien­yl) fragment [Pb—Mo = 3.0589 (5) Å] and a chelating acetate (Ac) group. Additionally, the [{Cp(CO) 3 Mo}PbAc] units are linked along [100] by Pb—O(acetate) inter­actions, giving a ladder-type polymeric structure composed of PbCO 2  and Pb 2 O 2  four-membered rings. The {Cp(CO) 3 Mo} units attached to the Pb II  atom occupy terminal positions at opposite sides of the slightly puckered lead acetate chain. The angle between the Pb—Mo bond vector and the central chain plane is 67.8 (2)°.

acta crystallographica. section e

catena-Poly[[tricarbonyl-1κ3C-(1η5-cyclopentadienyl)lead(II)molybdenum(0)](Mo—Pb)-μ3-acetato-2′:2:2′′κ4O:O,O′:O′]