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The asymmetric unit of the title compound, {[MgNa 2 (C 10 H 4 O 8 ) 2 (H 2 O) 8 ]·2H 2 O}  n  , contains one octa­hedrally coordin­ated Mg II  atom (site symmetry 2/ m ), one octahedrally coordinated Na I  atom (site symmetry 2) and one half of the dihydrogen benzene-1,2,4,5-tetra­carboxyl­ate (btec) ligand, the second half of the ligand being generated by a twofold rotation axis. The basic framework of the title compound features infinite (–Na–Na–Mg–)  n   chains along [10-1] with the metal cations bridged by the coordinating water molecules. The chains are isolated from each other by μ 4 -bridging btec ligands, which form inter­molecular O—H⋯O hydrogen bonds to uncoordinated water mol­ecules and the coordinated water mol­ecules of a neighbouring chain. In each btec ligand, there are also intramolecular O—H⋯O hydrogen bonds.

Poly[[hexa-μ-aqua-diaquabis(μ4-dihydrogen benzene-1,2,4,5-tetracarboxylato)magnesiumdisodium] dihydrate]