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In the title complex, [Ni(C 6 H 6 N 3 O)(NCS)(C 6 H 7 N 3 O)(H 2 O)] or [Ni(mpko)(SCN)(mpkoH)(H 2 O)] [where mpkoH = 1-(pyrazin-2-yl)ethanone oxime], the Ni II  cation is in a slightly distorted octa­hedral geometry, being coordinated in the equatorial plane by four N atoms from two different mpkoH ligands, one of which is deprotonated, and by one N atom from a thio­cyanate anion and one O atom from a water mol­ecule in the axial positions. There is an intra­molecular O—H⋯O hydrogen bond involving the oxime units of the two ligands. In the crystal, a three-dimensional supra­molecular architecture is formed by O—H⋯O and O—H⋯N hydrogen bonds.

acta crystallographica. section e

Aqua[1-(pyrazin-2-yl)ethanone oximato-κ2N,N′][1-(pyrazin-2-yl)ethanone oxime-κ2N,N′](thiocyanato-κN)nickel(II)