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In the title compound, [Cu(C 7 H 7 N 2 O)(C 7 H 8 N 2 O)(H 2 O)]ClO 4 ·H 2 O, the Cu II  ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules and ions are linked by O—H⋯O hydrogen-bonding inter­actions, forming chains along the  a  axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio.

Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]copper(II) perchlorate monohydrate