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A new polymorph of the title compound, [Pd 2 (C 8 H 18 P) 2 (C 8 H 19 P) 2 ], has been found. It belongs to the triclinic  P -1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992  ▶ ),  J. Organo­met. Chem.   423 , 263–270] crystallizes in the monoclinic  C 2/ c  space group. The title compound features a dinuclear palladium complex with a planar central Pd 2 (μ-P) 2  core (r.m.s. deviation = 0.003 Å). The Pd—Pd distance of 2.5988 (5) Å is within the range of a Pd I —Pd I  bond. The mol­ecules of both polymorphs are located on a crystallographic centre of inversion. The mol­ecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different.

A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)]