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In the title compound, [Fe(C 5 H 6 ClO 2 ) 3 ], the Fe III  cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in a slightly distorted octa­hedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The  trans  O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding  cis  angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, mol­ecules are linked  via  C—H⋯Cl inter­actions.

Tris(3-chloropentane-2,4-dionato-κ2 O,O′)iron(III)

Tris(3-chloropentane-2,4-dionato-κ² O,O′)iron(III)