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In the title complex, [Cu(C 16 H 15 NO 3 )(C 10 H 8 N 2 )]·3H 2 O, the Cu II  atom is five coordinated by  O , N , O ′-donor atoms of the Schiff base ligand and by two N atoms of the 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (011) by O—H⋯O hydrogen bonds.

acta crystallographica. section e

(2,2′-Bipyridine-κ2 N,N′){N-[(2-oxidonaphthalen-1-yl-κO)methylidene]-<scp>L</scp>-valinato-κO}copper(II) trihydrate

(2,2′-Bipyridine-κ2 N,N′){N-[(2-oxidonaphthalen-1-yl-κO)methylidene]-L-valinato-κO}copper(II) trihydrate

(2,2′-Bipyridine-κ² N,N′){N-[(2-oxidonaphthalen-1-yl-κO)methylidene]-L-valinato-κO}copper(II) trihydrate