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In the cation of the title salt, C 28 H 27 O 3 S + ·CF 3 O 3 S − , the dihedral angle between the naphthalene ring system and the –C(=O)—O– plane is 80.39 (9)°. The three methyl groups of the  tert -butyl group are each disordered over two orientations with an occupancy ratio of 0.712 (18):0.288 (18).

[4-(2-tert-Butoxy-2-oxoethoxy)naphthalen-1-yl]diphenylsulfonium trifluoromethanesulfonate