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In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions. Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

acta crystallographica. section e

Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ3 N 2,N 3,N 4]ytterbium(III) chloride