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In the title compound, (C 6 H 17 N 3 ) 2 [Ge 2 S 6 ], the dimeric [Ge 2 S 6 ] 4−  anion is formed by two edge-sharing GeS 4  tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N—H⋯S hydrogen bonds.

Bis[4-(2-azaniumylethyl)piperazin-1-ium] di-μ-sulfido-bis[disulfidogermanate(II)]